Tuesday 13 June 2017

Hydrocarbons

UNIT 21: Hydrocarbons

Classification, isomerism, IUPAC nomenclature, general methods of preparation, properties and reactions.

Alkanes - Conformations: Sawhorse and Newman projections (of ethane); Mechanism of halogenation of alkanes.

Alkenes - Geometrical isomerism; Mechanism of electrophilic addition: addition of hydrogen, halogens, water, hydrogen halides (Markownikoff’s and peroxide effect); Ozonolysis, oxidation, and polymerization.

Alkynes - Acidic character; Addition of hydrogen, halogens, water and hydrogen halides; Polymerization.

Aromatic hydrocarbons - Nomenclature, benzene - structure and aromaticity; Mechanism of electrophilic substitution: halogenation, nitration, Friedel - Craft’s alkylation and acylation, directive influence of functional group in mono-substituted benzene
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